Colour selection is one of the vital things to be
considered in the plastics industry. Colour is an integral part of the
plastic material and it should not be considered as an after thought. The
whole system of colouring has to be deal with using what is called a total
systems approach. No doubt the colour enhances the part's functionality, but
it has also the potential to degrade certain material properties like impact
strength, if not properly applied.
The colourants that are used in the Plastic Industries are the dyes and
pigments. Both dyes and pigments exhibit colour through the process of
visible light absorption and scattering. Typically colour formulations
generally have four colourants. Black and white are used basically to
control the value and Chroma, while two coloured pigments or dyes are
applied to establish the Hue. The resulting color that is achieved is
governed by the laws of subtractive mixing, the same law that is used in
printing and painting.
Dyes that are used in the plastics industry must be very strong, show good
heat stability and be transparent. Typically the dyes are used to tint or
shade a resin. In the plastics industry dyes are limited in use, as such
they can be used for only a selected number of resins. Pigments used in this
industry can be organic or inorganic. While pigments offer more choices to
the manufacturers due to its opacifying ability, broader chroma range, and
better heat stability for most of the resins. Pigments are generally
dispersed within a resin matrix, while dyes solubilize in the resin.
Titanium Dioxide is a pigment that has a wide use in Plastics industry. It
is used to make the plastics more whiter, brighter and durable.
It is actually the base polymer that dictates the choice
of the colorant selected. Pigments are typically used in polyolefins as most
of dyes show a tendency to migrate in polyolefins. While Dyes are often
successfully used with polycarbonate, polystyrene, acrylic, and other types
polymers because of their color strength and transparency. The final word is
whatever be the colorant selected it must show compatibility with the base
resin. This is in order to prevent a color shift occurring over time.
Let us look at the properties of few of the colourants that constitutes
both dyes and pigments:
| Type of Effect |
Pearlescent |
Metallic |
Fluorescent |
Phosphorescent |
Thermochromic |
Photochromic |
| Cost |
Low |
Low |
Low-High |
Medium |
High |
High |
| Polymer compatibility |
All |
All |
Dyes: PMMS, PET, ABS, Pigments:PE, PP |
PMMS, PE, PS |
All |
All |
| Durability |
Excellent |
Excellent |
Fair |
Good |
Fair |
Fair |
Notes:
PMMA: Poly Methyl Methacrylate
PET: Polyethylene Terephthalate
SAN: Styrene-Acrylonitrile Copolymer
ABS: Acrylonitrile Butadiene Styrene